Trace metalsnutrient salts relationship in coastal seawater of Alexandria
Trace metalsnutrient salts relationship in coastal seawater of AlexandriaH.I.Emara, M.A. Shiradah, Th.H. Moustafa and M.S. ElDeek
National Institute of Oceanography and Fisheries, Kayet
Bey, Alexandria, Egypt
Abstract
Sea water samples, collected from the Eastern Harbour
(EH) and ElMex Bay of Alexandria City during the period
from November 1987 to January 1989, showed that the
variations of the concentration of metals, especially
Co, Ni and Cr in ElMex Bay as well as Ni and Cr in
EH are obviously related to seasonal variations of
the seawater density ('sigma't). During colder months,
the water column of the EH is concentrated with Ni
and Cr. Manganese, iron and zinc showed analogous behaviour
to Ni and Cr but with a decrease in concentration during
November 1988 instead of the increase. At ElMex Bay,
where the density of water is lower by 6.9 than the
average values of EH, the peaks of metals Co, Ni and
Cr as well as 'sigma't were shifted to April. Phosphate
showed similar behaviour to 'sigma't but with two peaks
in February and June. During Warmer months (AugustSeptember)
the metal content in both areas decreased to minimum.
The normal relationship between micronutrients and
trace metals Mn, Cu, Ni, Zn and Cr holds well for the
sea water of the Eh and to a less extent ElMex Bay
and it is obvious that there is a trace metalsphosphate
covariations and a linear regression equations were
estimated. Organic phosphorus also showed significant
good correlation with Fe, Mn, Co and Cr, as well as
Fe and Cu. Concentration of trace metals versus salinity
showed a decrease of Fe and Mn when moving from low
to higher salinities. In contrast, Cd and Pb showed
higher concentrations at higher salinities which may
be attributed to the release of these elements from
bottom or suspended sediments. Phosphate and nitrate
reflect higher levels at low and intermediate salinities.
The daily contribution of trace metals and nutrients
in kilograms that fluxes to the sea at ElMex Bay were
estimated as: 867, 376, 107, 38, 10, 2.8, 2.6, 2.5,
1.3, 9140, 26308, 878 for Fe, Zn, Mn, Cu, Cd, Pb, Cr,
Ni, Co, phosphate, organic phosphorus and nitrate,
respectively.